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Fast Pulling of n-Type Si Ingots for Enhanced Si Solar Cell Production

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Abstract

Reducing the manufacturing costs of silicon substrates is an important issue in the silicon-based solar cell industry. In this study, we developed a high-throughput ingot growth method by accelerating the pulling speed in the Czochralski process. By controlling the heat flow of the ingot growth chamber and at the solid-liquid interfaces, the pulling speed of an ingot could be increased by ~ 15% compared to the conventional method, while retaining high quality. The wafer obtained at a high pulling speed showed an enhanced minority carrier lifetime compared with conventional wafers, due to the vacancy passivation effect, and also demonstrated comparable bulk resistivity and impurities. The results in this work are expected to open a new way to enhance the productivity of Si wafers used for Si solar cells, and therefore, to reduce the overall manufacturing cost.

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References

  1. Bekhet, H.A., Matar, A., Yasmin, T.: CO2 emissions, energy consumption, economic growth, and financial development in GCC countries: dynamic simultaneous equation models. Renew. Sust. Energ. Rev. 70, 117 (2017)

    Article  Google Scholar 

  2. Seo, J.W., Cha, J.S., Park, K.: Enhanced thermoelectric properties of Ca1-xSm x Mn1-yW y O3-δ for power generation. Electron. Mater. Lett. 12, 113 (2016)

    Article  Google Scholar 

  3. Pambudi, N.A., Itaoka, K., Yamakawa, N.: Future Japan power generation sector by introducing hydrogen plant with 80% CO2 emission reduction target : a preliminary analysis. In: International Conference on Sustainable Energy Engineering and Application (ICSEEA), p. 66, IEEE Inst. Elec. Electron. Eng. Inc., Tangerang, Indonesia (2016)

  4. Ebong, A., Chen, N., Unsur, V., Chowdhury, A., Damiani, B.: Innovative front grid design, four-streets and five-busbars (4S-5BB), for high efficiency industrial Al-BSF silicon solar cell. IEEE Electr. Device Lett. 37, 459 (2016)

    Article  Google Scholar 

  5. Baik, S.S., Pang, I.S., Kim, J.M., Kim, K.H.: Improvement of minority carrier life time in N-type monocrystalline Si by the Czochralski method. Electron. Matter. Lett. 12, 426 (2016)

    Article  Google Scholar 

  6. Huang, H., Lv, J., Bao, Y., Xuan, R., Sun, S., Sneck, S., Li, S., Modanese, C., Savin, H., Wang, A., Zhao, J.: 20.8% industrial PERC solar cell: ALD Al2O3 rear surface passivation, efficiency loss mechanisms analysis and roadmap to 24%. Sol. Energ. Mat. Sol. Cells 161, 14 (2017)

    Article  Google Scholar 

  7. Abenante, L.: Comments on “20.8% PERC solar cell on 156 mm x 156 mm P-type multicrystalline silicon substrate”. IEEE J. Photovolt. 7, 409 (2017)

    Article  Google Scholar 

  8. Kim, K.H., Baik, S.S.: Optimization of pulling speed for decreasing thermal stress in different quartz crucible size with Czochralski method. In: 42nd IEEE Photovoltaic Specialists Conference (PVSC), p. 1, IEEE Inst. Elec. Electron. Eng. Inc., New Orleans, USA (2015)

  9. Liu, L., Kakimoto, K.: Effects of crystal rotation rate on the melt–crystal interface of a CZ-Si crystal growth in a transverse magnetic field. J. Cryst. Growth 310, 306 (2008)

    Article  Google Scholar 

  10. Noghabi, O.A., M’Hamdi, M., Jomaa, M.: Effect of crystal and crucible rotations on the interface shape of Czochralski grown silicon single crystals. J. Cryst. Growth 318, 173 (2011)

    Article  Google Scholar 

  11. Su, W., Zuo, R., Mazaev, K., Kalaev, V.: Optimization of crystal growth by changes of flow guide, radiation shield and sidewall insulation in Cz Si furnace. J. Cryst. Growth 312, 495 (2010)

    Article  Google Scholar 

  12. Sim, B.C., Jung, Y.H., Lee, H.W.: Effect of the ingot cooling on the grown-in defects in silicon Czochralski growth. Jpn. J. Appl. Phys. 48, 105503 (2009)

    Article  Google Scholar 

  13. Kim, K.H., Baik, S.S.: Decrease of thermal donors in Si single crystal by Czochralski method. Sci. Adv. Mater. 8, 632 (2016)

    Article  Google Scholar 

  14. Sinno, T., Dornberger, E., von Ammon, W., Brown, R.A., Dupret, F.: Defect engineering of Czochralski single-crystal silicon. Mater. Sci. Eng. R Rep. 28, 149 (2000)

    Article  Google Scholar 

  15. Scheil, E.: Z. metallk. 34, 70 (1942)

    Google Scholar 

  16. Shimura, F.: Semiconductor Silicon Crystal Technology, p. 96. Academic Press Inc., San Diego (1989)

    Google Scholar 

  17. Green, M.A.: Solar Cells: Operating Principles, Technology, and System Applications, p. 92. Prentice-Hall Inc., Englewood Cliff (1982)

    Google Scholar 

  18. Xie, M., Ren, C., Fu, L., Qiu, X., Yu, X., Yang, D.: An industrial solution to light-induced degradation of crystalline silicon solar cells. Front. Energy 11, 67 (2017)

    Article  Google Scholar 

  19. Binns, M.J., Kearns, J., Good, E.A.: Impact of oxygen-related defects on lifetime degradation in N-type CCZ/CZ mono-crystalline silicon during cell processing. ECS Trans. 60, 1233 (2014)

    Article  Google Scholar 

  20. Hicks, T.W., Organ, A.E., Riley, N.: Oxygen transport in magnetic Czochralski growth of silicon with a non-uniform magnetic field. J. Cryst. Growth 94, 213 (1989)

    Article  Google Scholar 

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Acknowledgements

This work was supported by the Korea Institute of Energy Technology Evaluation and Planning (KETEP) and the Ministry of Trade, Industry & Energy (MOTIE) of the Republic of Korea (No. 20163030013700). This research was also supported by the Climate Change Research Hub (CRH) of KAIST (Grant No. EEWS-2017-N11170057).

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Correspondence to Kwanghun Kim, Sangwoo Ryu or Jihun Oh.

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Kim, K., Park, S., Park, J. et al. Fast Pulling of n-Type Si Ingots for Enhanced Si Solar Cell Production. Electron. Mater. Lett. 14, 461–466 (2018). https://doi.org/10.1007/s13391-018-0040-3

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  • DOI: https://doi.org/10.1007/s13391-018-0040-3

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